Olefin polymerization catalyst and process of polymerization

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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526124, 526125, 526127, 526128, 526142, 526143, 526351, 526352, 585532, C07C 230, C08F 402

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active

051460289

ABSTRACT:
Improved lower .alpha.-olefin polymerization catalysts are produced from an organoaluminum cocatalyst, a selectivity control agent and a specified magnesium-containing, titanium-containing, halide-containing procatalyst. The procatalyst is produced from an electron donor, tetravalent titanium halide and a complex alkoxide compound formed from magnesium alkoxide, titanium alkoxide and a phenolic compound. The catalyst is utilized to produce poly-.alpha.-olefin in good yield, which polymer is characterized by a relatively low xylene solubles content and a relatively high bulk density.

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