Olefin polymerization catalyst and process for olefin polymeriza

Details Olefin polymerization catalyst and process for olefin polymeriza Olefin polymerization catalyst and process for olefin polymeriza

1994-12-27

1997-05-06

Smith, Edward J.

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Plural component system comprising a - group i to iv metal...

502103, 502117, 502153, 502154, 502127, 502131, 502133, 502160, 526114, 526115, 526116, 526126, C08F 4622, C08F 4623, C08F 1000

Patent

active

056271174

ABSTRACT:
Disclosed in an olefin polymerization catalyst comprising a transition metal compound having at least two transition metals in which at least one of said metals is bonded to a ligand having a cyclopentadienyl skeleton, at least one of said metals is selected from Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W and lanthanoid metals and at least on of the others is selected from the specific transition metals; and an organoaluminum oxy-compound or an organoboron compound. Corresponding to the kind of the metal combined with said metal selected from Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W and lanthanoid metals, the olefin polymerization catalyst exhibit a property to give polymers having a wide molecular weight distribution in spite of the catalyst system using one kind of a transition metal compound, or to give polymers having high molecular weight and be excellent in the polymerization activity at low polymerization temperature.

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