Olefin polymerization catalyst

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

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502113, 526114, 526116, C08F 464

Patent

active

045254680

ABSTRACT:
High activity catalysts for the polymerization of ethylene and other .alpha.-olefins are made by contacting a soluble magnesium compound of the general formula Mg(OSiR.sup.1 R.sup.2 R.sup.3).sub.2, wherein each of R.sup.1, R.sup.2, and R.sup.3 is, independently, alkyl, alkoxy or aryl with a metal alkoxide, or a mixture of a titanium tetraalkoxide with an alkoxide of another transition metal, in a saturated aliphatic hydrocarbon solution, followed by chlorination and precipitation by a suitable chlorinating agent. These catalysts show high activity for the polymerization of ethylene, especially under slurry polymerization conditions.

REFERENCES:
patent: 3135809 (1964-06-01), Bosmajian
patent: 4440869 (1984-04-01), Shannon et al.

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