Olefin polymerisation catalyst

Details Olefin polymerisation catalyst Olefin polymerisation catalyst

2006-07-18

2006-07-18

Harlan, Robert D. (Department: 1713)

Catalyst, solid sorbent, or support therefor: product or process

Catalyst or precursor therefor

Organic compound containing

C502S167000, C526S161000, C526S171000, C526S172000, C526S348000, C526S351000, C526S352000

Reexamination Certificate

active

07078363

ABSTRACT:
The invention concerns a catalyst for olefin polymerisation, of formula (I) wherein: E is an oxygen or sulphur atom; X is a phosphorus, arsenic or antimony atom; M is a nickel, palladium or platinum atom comprising a non-attributed valency; a is 1 or 2; R1, R2, R3, identical or different can be selected among hydrogen, alkyl, cycloalkyl, aryl, alkylaryl, arylalkyl radicals, the hydroxyl radical, the alkoxide radicals (with 1 to 20 carbon atoms), the groups —C(O)OR′—, —SO3Y; and Z represents a hydrocarbon radical comprising 2 to 3 carbon atoms; R represents a hydrocarbon radical of valency a, provided that at least one of the radicals Z or R bears at least an electroattractive substituent

REFERENCES:
patent: 3635937 (1972-01-01), Bauer et al.
patent: 3637636 (1972-01-01), Bauer et al.
patent: 3647914 (1972-03-01), Glockner et al.
patent: 3661803 (1972-05-01), Bauer et al.
patent: 3686159 (1972-08-01), Bauer et al.
patent: 4293727 (1981-10-01), Beach et al.
patent: 4301318 (1981-11-01), Beach et al.
patent: 4529554 (1985-07-01), Beach et al.
patent: 4716205 (1987-12-01), Klabunde
patent: 5929181 (1999-07-01), Makovetsky et al.
patent: 6197984 (2001-03-01), Makovetsky et al.
patent: 60319 (1994-07-01), None
patent: 2 784 110 (2000-04-01), None
patent: 2814169 (2002-03-01), None
patent: WO 98/56837 (1998-12-01), None
Klabunde U., et al., “Reaction of nickel polymerization catalysts with carbon monoxide”, J. Organomet. Chem. (1987), 334 (1-2), 141-56, XP-001002462.
Jacobson S. et al. “Nucleophilic Attach on Co-ordinated Phosphinoacetylenes: Products from the Hydrolysis of Cis-PDC12 (PH2PC CCF3) and the X-Ray Structure of a 1-Diphenylphosphino-3, 3, 3-Trifluoropropen-2-Olato Complex”, Journal of the Chemical Society, Chemical Communicatins, Chemical Society. Letchworth, GB, No. 7, 1974, pp. 668-669, XP001002443 ISSN: 0022-4936.
Mueller, Ulrich, et al. “Ph2PCH2C (CF3)201NiH(Pcy3) (Cy = cyclohexyl): proof of a nickel hydride mechanism of ethane oligomerization”, Angew. Chem. (1989), 101(8), 1066-7, XP001006327, p. 1066.
U. Klabunde, et al., “Ethylene Homopolymerization with P, O-Chelated Nickel Catalysts”, Journal of Polymer Science, Part A: Polymer Chemistry, vol. 25, pp. 1989-2003 (1987).
U. Klabunde, et al., “Nickel Catalysis for Ethylene Homo-And-Co-Polymerization”, Journal of Molecular Catalysis, 41 (1987) pp. 123-134.
A. Held, et al., Coordination Polymerization of Ethylene in Water by Pd(II) and Ni(II) Catalysts, Chem. Comm., (2000), pp. 301-302.

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