Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Organic compound containing
Patent
1985-09-24
1988-01-19
Garvin, Patrick P.
Catalyst, solid sorbent, or support therefor: product or process
Catalyst or precursor therefor
Organic compound containing
502167, 502170, 502201, 502204, 502206, 502207, 502209, 502210, 502211, 502213, 502215, 502217, 502218, 502219, 502220, 502221, 502228, 502230, 502241, 502242, 502245, 502254, 502255, 502262, 502305, 502308, 502313, 502314, 502316, 502324, 502326, 502331, 502338, 502339, B01J 3102
Patent
active
047204745
ABSTRACT:
The addition of redox-active metal components and ligands, alternatively or simultaneously, results in increased conversion and selectivity in the palladium-catalyzed oxidation of olefins to carbonyl products in the presence of polyoxoanions. In preferred modes, heteropolyoxoanions and isopolyoxoanions containing tungsten, molybdenum and vanadium, individually or in combination, are described. The use of copper as the redox-active metal component shows reduced allylic reactivity. The elimination of chloride from the catalyst system provides substantial engineering advantages over the prior art, particularly, the reduction of corrosion and chloro-organic by-product formation. The use of redox-active metal components and/or ligands makes the palladium-polyoxoanion catalyst system industrially practicable.
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De Deken Jacques C.
Fellmann Jere D.
Kipnis Lyubov S.
Saxton Robert J.
Vasilevskis Janis
Catalytica Associates
Garvin Patrick P.
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