Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...
Patent
1992-11-04
1994-02-08
Garvin, Patrick P.
Chemistry of hydrocarbon compounds
Unsaturated compound synthesis
By addition of entire unsaturated molecules, e.g.,...
585520, C07C 202
Patent
active
052849899
ABSTRACT:
A method for producing substantially linear hydrocarbons by oligomerizing a lower olefin at elevated temperature and pressure which comprises contacting the lower olefin under oligomerization/polymerization conditions with constrained intermediate pore siliceous acidic zeolite, e.g., ZSM-22, -23 or -35, having Bronsted acid activity; wherein the zeolite has acidic pore activity and wherein the zeolite surface is rendered substantially inactive for acidic reactions. The zeolite surface can be inactivated by contact with dicarboxylic acid, e.g., oxalic acid. The olefin oligomers may be used as alkylating agents to prepare biodegradable alkylbenzenes and alkylphenylsulfonates.
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Apelian Minas R.
Boulton James R.
Fung Anthony S.
Garvin Patrick P.
Hobbes Laurence P.
Irzinski E. D.
McKillop Alexander J.
Mobil Oil Corporation
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