Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...
Patent
1995-06-16
1997-07-22
Caldarola, Glenn A.
Chemistry of hydrocarbon compounds
Unsaturated compound synthesis
By addition of entire unsaturated molecules, e.g.,...
585500, 585510, 585515, 585520, 585526, 585529, C07C 208
Patent
active
056505485
ABSTRACT:
Alpha-olefin oligomer is prepared by contacting an alpha-olefin monomer which contains from about 6 to about 20 carbon atoms with a catalyst system comprising boron trifluoride, a protic promoter, and an organic sulfone, sulfoxide, carbonate, thiocarbonate, or sulfonate. Oligomer containing as much as 50% or more of dimer can be produced at high conversions, at modest reaction temperatures, and in acceptably short reaction periods.
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Irwin Robert G.
Theriot Kevin J.
Amoco Corporation
Caldarola Glenn A.
DiSalvo Joseph
Hensley Stephen L.
Wood Elizabeth D.
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