Olefin isomerization using an extruded alumina paste supporting

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By double-bond-shift isomerization

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585670, C07C 524

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active

042096553

ABSTRACT:
Isomerizable hydrocarbons including paraffins, cycloparaffins, olefins and alkyl aromatics are isomerized by contacting the hydrocarbon at isomerization conditions with a catalytic composite comprising a platinum group metal on an alpha-alumina monohydrate support wherein said support is prepared by admixing an alpha-alumina monohydrate with an aqueous ammoniacal solution having a pH of at least about 7.5 to form a stable suspension and commingling said suspension with a salt of a strong acid to form an extrudable paste or dough. Upon extrusion, the extrudate is dried and calcined to form said alumina support.

REFERENCES:
patent: 3723554 (1973-03-01), Wilhelm
patent: 4018845 (1977-04-01), Rausch
patent: 4098874 (1978-07-01), Mitsche et al.

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