Olefin isomerization process

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By double-bond-shift isomerization

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585670, 585671, C07C 523, C07C 525

Patent

active

053650085

ABSTRACT:
An improved process is disclosed for the isomerization of butenes and/or pentenes using a catalyst comprising a silicoaluminophosphate molecular sieve containing noncondensed silica. It is of particular interest to increase the proportion of olefins containing tertiary carbons in the product with low formation of undesirable by-products. Product olefins may be further processed to obtain ethers, which enjoy high current interest as components for reformulated gasoline.

REFERENCES:
patent: 4684757 (1987-08-01), Avidan et al.
patent: 5132484 (1992-07-01), Gajda
patent: 5191146 (1993-03-01), Gajda et al.

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