Olefin ethylation process

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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585510, 585643, 585645, C07C 202

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active

050435167

ABSTRACT:
The present invention provides a process for the ethylation of detergent-range olefins to produce higher molecular weight olefins which comprises reacting ethylene with a detergent-range olefin in the presence of a catalyst comprising an alumina having a sodium content per unit surface area of less than about 3.times.10.sup.-5 g/m.sup.2.

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Pines, et al., "Sodium Catalyzed Reactions, II., Side-Chain Ethylation of Alkyl Aromatic Hydrocarbons Catalyzed by Sodium," J. of the American Chemical Society, vol. 77, 1955, pp. 554-559.

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