Olefin epoxidation using a carbon molecular sieve impregnated wi

Details Olefin epoxidation using a carbon molecular sieve impregnated wi Olefin epoxidation using a carbon molecular sieve impregnated wi

1993-09-23

1994-06-07

Evans, Joseph E.

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

C07D30119, C07D30304

Patent

active

053191145

ABSTRACT:
Olefins are selectively converted to epoxides by reacting with an organic hydroperoxide in the presence of a heterogeneous catalyst comprised of a carbon molecular sieve containing a Group IVA, VA, VIA, or VIIA transition metal such as molybdenum.

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"Carbonaceous Absorbents As Catalyst Supports", Russell S. Drago, Steven K. Showalter & Gerald C. Grunewald, American Chemical Society in Abstracts of Papers, Part 2, 206th ACS National Meeting, Aug. 22-27, 1993.
Chemical & Pharmaceutical Bulletin, vol. 33, No. 9, Sep. 1985 Itoi et al.
1985 The Chemical Society of Japan, Bull. Chem. Soc. Jpn. 58, 31933196 (1985) "Tungstic Acid-Tributyltin Chloride on a Charcoal Catalyst in the Epoxidation of Alkenes with Hydrogen Peroxide", Itoi et al.
Chem. Pharm. Bull 32(2) 418-423 (1984) "Epoxidation of Alkenes with Hydrogen Peroxide in the Presence of Molybdenum Oxide-Tributyltin Chloride on Charcoal Catalysts", Itoi et al.
Chemistry Letters pp. 1375-1378, 1982, "The Epoxidation of Olefins with Hydrogen Peroxide on Molybdenium Blue-Charcoal Catalysts", Inoue et al.
J. Am. Chem. Soc., 1991, 113, 1636-1639-"Carbon Molecular Sieves As Catalysts and Catalyst Supports", G. C. Grunewald & R. S. Drago.
Journal of Molecular Catalysis 7, (1980) 107-126, R. A. Sheldon, "Synthetic & Mechanistic Aspects of Metal-Catalysed Epoxidation with Hydroperoxides".

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