Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By double-bond-shift isomerization
Patent
1988-07-26
1989-03-21
Pal, Asok
Chemistry of hydrocarbon compounds
Unsaturated compound synthesis
By double-bond-shift isomerization
585664, C07C 525
Patent
active
048145424
ABSTRACT:
A process for olefin bond isomerization by means of a gamma alumina-based catalyst containing SiO.sub.2 and oxides of a metal chosen from those of Group II A and/or VIII and/or III B and/or Lanthanides, with particular molar ratios between the various oxides. The catalyst is thermally stable, and in the conversion of butene-2 to butene-1 enables butene-1 to be obtained with an isobutene content below the allowable limits for butene-1 grade polymerization.
REFERENCES:
patent: 3467727 (1969-09-01), Kahn
patent: 3479415 (1969-11-01), Shule
patent: 3864424 (1975-02-01), Brennan et al.
patent: 4217244 (1980-08-01), Montgomery
patent: 4229610 (1980-10-01), Myers et al.
Ancillotti Francesco
Forlani Orfeo
Notari Bruno
Pal Asok
Snamprogetti S.p.A.
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