Obtention of digitoxigenin from neriifolin and 2'-acetylneriifol

Details Obtention of digitoxigenin from neriifolin and 2'-acetylneriifol Obtention of digitoxigenin from neriifolin and 2'-acetylneriifol

1974-09-16

1976-01-20

Gotts, Lewis

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

424182, C07J 1900

Patent

active

039337910

ABSTRACT:
Process for degrading the glycoside neriifolin and its acetate to the cardenolide digitoxigenin. Novel intermediates are also described.

REFERENCES:
patent: 2752372 (1956-06-01), Reichstein
patent: 3682891 (1972-08-01), Radscheit et al.
Fieser and Fieser, Reagents for Organic Syn., Wiley and Sons, Inc. 1967, p. 146.
Wagner and Zook, Synthetic Org. Chemistry, Wiley and Sons, Inc., New York, 1953, pp. 34-35.

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