Obtaining aqueous solution from insoluble metal oxide

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Group viib metal

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423DIG4, 423544, 423605, 75 2, 75101R, 75121, 75114, 75115, C01G 4500

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046456503

ABSTRACT:
This method of obtaining an aqueous solution of metal values from an insoluble metal oxide is possible where the metal has a lower oxidation number in the solution than in the insoluble oxide, for example manganese (+2 and +4 respectively).
The oxide, such as MnO.sub.2, is treated with hot mineral acid such as HCl in the presence of coal. After some hours, the liquid comes to contain most of the manganese as dissolved Mn(II) ion.

REFERENCES:
Agarwal, J. C. et al, "Processing of Ocean Nodules: A Technical and Economic Review, J. of Mines, vol. 28, No. 4, Apr., 1976.

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