Nucleating agents for polyhydroxyalkanoates

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

Reexamination Certificate

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Details

C264S176100, C264S212000, C264S239000, C264S291000, C264S330000, C264S464000, C524S081000, C524S086000, C524S186000, C524S233000, C525S437000, C525S450000, C525S540000

Reexamination Certificate

active

11224805

ABSTRACT:
The present invention provides a process for crystallizing a polymer having at least 20 mole percent of hydroxyalkanoate repeat units, comprising admixing the polymer and a compound of the formula R1—C(O)N(R2)2, R1—C(O)NH—(R3)—NHC(O)—R1, R1—NHC(O)NH—(R3)—NHC(O)NH—R1, R1—NHC(O)—R2, R1—NHC(O)—(R3)—C(O)NH—R1, R1—C(O)NH—(R3)—C(O)NH—R1, R1—NHC(O)NH—(R3)—C(O)NH—R1, R1—NHC(O)NH—(R3)—NHC(O)—R1, or a combination thereof, at a first temperature, which is from about 5° C. to about 15° C. above the melting point of the polymer; and cooling the polymer at a second temperature, which is from about the glass transition temperature of the polymer to about the melting point of the compound. The present invention also provides a composition comprising a polymer having at least about 20 mole percent of hydroxyalkanoate repeat units, and a compound of the formula R1—C(O)N(R2)2, R1—C(O)NH—(R3)—NHC(O)—R1, R1—NHC(O)NH—(R3)—NHC(O)NH—R1, R1—NHC(O)—R2, R1—NHC(O)—(R3)—C(O)NH—R1, R1—C(O)NH—(R3)—C(O)NH—R1, R1—NHC(O)NH—(R3)—C(O)NH—R1, R1—NHC(O)NH—(R3)—NHC(O)—R1, or a combination thereof.

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International Search Report mailed Dec. 12, 2005, 5 pages.

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