Nucleating additive formulations of bicyclo[2.2.1]heptane...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – At least one aryl ring which is part of a fused or bridged...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C524S321000, C524S394000, C524S397000, C524S400000, C524S492000, C524S445000, C524S451000, C524S582000

Reexamination Certificate

active

06946507

ABSTRACT:
Milled, small particle size, solid bicyclo[2.2.1]heptane dicarboxylate salt-containing thermoplastic nucleating additive formulations further comprising at least one anticaking agent for improved haze reduction, improved nucleation performance, and prevention of potential cementation (via agglomeration) of the salt component present therein are provided. Such small particle size dicarboxylate salts provide desirable properties within thermoplastic articles, particularly as nucleating agents, but apparently suffer from certain clarity issues and agglomeration problems (due to the flat and thin plate structures of such compounds and the propensity they exhibit to cohere to each other during storage), making utilization thereof less desirable for certain applications. Thus, an improvement has been provided to permit full benefit of the excellent crystallization temperatures, stiffness, and calcium stearate compatibility such dicarboxylate salts accord within target low haze thermoplastics. Furthermore, unexpected improvements in dusting reduction have been found upon the utilization of such anticaking additives in combination with the aforementioned nucleating salts. Thermoplastic additive compositions and methods of producing thermoplastics with such nucleator/anticaking additive combinations are also contemplated within this invention.

REFERENCES:
patent: 3201363 (1965-08-01), Spurlin et al.
patent: 3207736 (1965-09-01), Wijga et al.
patent: 3234233 (1966-02-01), Bolger et al.
patent: 3320267 (1967-05-01), Poos et al.
patent: 3367926 (1968-02-01), Voeks et al.
patent: 3527736 (1970-09-01), Averink et al.
patent: 3793401 (1974-02-01), Nield et al.
patent: 3829450 (1974-08-01), Schmerling et al.
patent: 3873643 (1975-03-01), Wu et al.
patent: 3882194 (1975-05-01), Krebaum et al.
patent: 3928687 (1975-12-01), Wada et al.
patent: 3933779 (1976-01-01), Baron et al.
patent: 3941746 (1976-03-01), Stephen et al.
patent: 3954913 (1976-05-01), Uebele et al.
patent: 4039491 (1977-08-01), Ikeda et al.
patent: 4134895 (1979-01-01), Roth et al.
patent: 4134927 (1979-01-01), Tomoshige et al.
patent: 4417999 (1983-11-01), Duffy
patent: 4452942 (1984-06-01), Shida et al.
patent: 4476184 (1984-10-01), Lubowitz et al.
patent: 4503219 (1985-03-01), Reffert et al.
patent: 4704421 (1987-11-01), Teskin
patent: 4739017 (1988-04-01), Tabor et al.
patent: 4778837 (1988-10-01), Waterman et al.
patent: 4801637 (1989-01-01), McCullough et al.
patent: 4829114 (1989-05-01), Trotoir et al.
patent: 5013778 (1991-05-01), Bath et al.
patent: 5135975 (1992-08-01), Rekers et al.
patent: 5342868 (1994-08-01), Kimura et al.
patent: 5491187 (1996-02-01), Ward et al.
patent: 5922793 (1999-07-01), Amos et al.
patent: 5929146 (1999-07-01), Amos et al.
patent: 5981636 (1999-11-01), Amos et al.
patent: 6096811 (2000-08-01), Amos et al.
patent: 6465551 (2002-10-01), Zhao et al.
patent: 6534574 (2003-03-01), Zhao et al.
patent: 6559211 (2003-05-01), Zhao et al.
patent: 6759124 (2004-07-01), Royer et al.
patent: 2003/0236332 (2003-12-01), Dotson et al.
patent: 1 544 851 (1970-05-01), None
patent: 1 694 914 (1972-03-01), None
patent: 0267 695 (1988-05-01), None
patent: 0336 573 (1989-03-01), None
patent: 2 075 549 (1971-09-01), None
patent: 2 656 620 (1991-07-01), None
patent: 2 290 296 (1995-12-01), None
patent: 53-40760 (1978-04-01), None
patent: 57-18682 (1982-01-01), None
patent: 58-160343 (1983-09-01), None
patent: 60-13837 (1985-01-01), None
patent: 61-17834 (1986-05-01), None
patent: 01-180514 (1989-07-01), None
patent: 03-076815 (1991-04-01), None
patent: 05-139460 (1993-06-01), None
patent: 07-173342 (1995-07-01), None
patent: WO 98/29494 (1998-07-01), None
patent: WO 02/077092 (2002-10-01), None
patent: WO 02/094759 (2002-11-01), None
H.N. Beck, “Heterogeneous Nucleating Agents of Polypropylene Crystallization”, Journal of Applied Polymer Science, vol. 11, pp. 673-685, 1967.
Overman et al., “An Annual Publication of Satisfactory Methods for the Preparation of Organic Chemicals.” Organic Synthesis, vol. 71, pp. 48-55, 1993.
Fillon et al., “Self-Nucleation and Recrystallization of Isotactic Polypropylene (alpha Phase) Investigated by Differential Scanning Calorimetry,” Journal of Polymer Science: Part B: Polymer Physics, vol. 31, pp. 1383-1393, 1993.
Fillon et al., “Self-Nucleation and Enhanced Nucleation of Polymers. Definition of a Convenient Calorimetric “Efficiency Scale” and Evaluation of Nucleating Additives in Isotactic Polypropylene (alpha phase),” Journal of Polymer Science: Part B: Polymer Physics, vol. 31 pp. 1395-1504, 1993.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Nucleating additive formulations of bicyclo[2.2.1]heptane... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Nucleating additive formulations of bicyclo[2.2.1]heptane..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Nucleating additive formulations of bicyclo[2.2.1]heptane... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-3396585

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.