Nuclear magnetic resonance spectrometer and method

Electricity: measuring and testing – Particle precession resonance – Using a nuclear resonance spectrometer system

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G01N 2700

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042849497

ABSTRACT:
A nuclear magnetic resonance technique that allows simultaneous temperature determination and spectral acquisition. The technique employs a modification of the lock circuit of a Varian XL-100 Spectrometer which permits accurate measurement of the difference in resonance frequency between a primary lock nucleus and another, secondary, nucleus. The field stabilization function of the main lock circuit is not compromised. A feedback signal having a frequency equal to the frequency difference is substituted for the normal power supply in the spectrometer's existing radio frequency transmitter to modulate that transmitter. Thus, the transmitter's radio frequency signal is enhanced in a frequency corresponding to the resonance peak of the secondary nucleus. Determination of the frequency difference allows the determination of temperature without interference with the observed spectrum. The feedback character of the circuit and the presence of noise make the circuit self-activating.

REFERENCES:
A. Ohte, "A Precision NOR Thermometer", IEEE Transactions on Inst. and Measurement, vol. IM-25, No. 4, pp. 357-362, Dec. 1976.
D. B. Utton, "Thermometry of NQR", Inst. Tech., vol. 23, No. 12, pp. 47-52, Dec. 1976.

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