Electricity: measuring and testing – Particle precession resonance – Using well logging device
Reexamination Certificate
2001-07-20
2003-07-22
Lefkowitz, Edward (Department: 2862)
Electricity: measuring and testing
Particle precession resonance
Using well logging device
C324S300000
Reexamination Certificate
active
06597171
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to investigations of rock samples, and more particularly relates to nuclear magnetic resonance (NMR) methods for determining characteristics of a fluid in a rock or earth formation.
BACKGROUND
NMR has been a common laboratory technique for over forty years and has become an important tool in formation evaluation. General background of NMR well logging can be found, for example, in U.S. Pat. No. 5,023,551 to Kleinberg et al., which is assigned to the same assignee as the present invention and herein incorporated by reference in its entirety.
NMR relies upon the fact that the nuclei of many chemical elements have angular momentum (“spin”) and a magnetic moment. In an externally applied static magnetic field, the spins of nuclei align themselves along the direction of the static field. This equilibrium situation can be disturbed by a pulse of an oscillating magnetic field (e.g., a RF pulse) that tips the spins away from the static field direction. The angle through which the spins are tipped is given by &thgr;=&ggr;B
1
t
p
/2, where &ggr; is the gyromagnetic ratio, B
1
is the linearly polarized oscillating field strength, and t
p
is the duration of the pulse. Tipping pulses of ninety and one hundred eighty degrees are most common.
After tipping, two things occur simultaneously. First, the spins precess around the direction of the static field at the Larmor frequency, given by &ohgr;
0
=&ggr;B
0
, where B
0
is the strength of the static field and &ggr; is the gyromagnetic ratio. For hydrogen nuclei, &ggr;/2&pgr;=4258 Hz/Gauss, so, for example, in a static field of 235 Gauss, the hydrogen spins would precess at a frequency of 1 MHz. Second, the spins return to the equilibrium direction according to a decay time, T
1
, which is known as the spin-lattice relaxation time. Because this spin-lattice relaxation occurs along the equilibrium direction, T
1
is also referred to as the longitudinal relaxation time constant.
Also associated with the spin of molecular nuclei is a second relaxation time, T
2
, called the spin-spin relaxation time. At the end of a ninety-degree tipping pulse, all the spins are pointed in a common direction perpendicular, or transverse, to the static field, and they all precess at the Larmor frequency. However, because of small fluctuations in the static field induced by other spins or paramagnetic impurities, the spins precess at slightly different frequencies, and the transverse magnetization dephases with a time constant T
2
, which is also referred to as the transverse relaxation time constant.
A standard technique for measuring T
2
, both in the laboratory and in well logging, uses a RF pulse sequence known as the CPMG (Carr-Purcell-Meiboom-Gill) sequence. As is well known, after a wait time that precedes each pulse sequence, a ninety-degree pulse tips the spins into the transverse plane and causes the spins to start precessing. Then, a one hundred eighty-degree pulse is applied that keeps the spins in the measurement plane, but causes the spins, which are dephasing in the transverse plane, to reverse direction and to refocus. By repeatedly reversing the spins using a series of one hundred eighty degree pulses, a series of “spin echoes” appear. The train of echoes is measured and processed to determine the irreversible dephasing time constant, T
2
. In well logging applications, the detected spin echoes have been used to extract oilfield parameters such as porosity, pore size distribution, and oil viscosity.
In theory, other laboratory NMR measurements may be applied in well-logging to extract additional information about the oilfield, but in practice, the nature of well-logging and the borehole environment make implementing some laboratory NMR measurements difficult. For example, inversion recovery is a common laboratory technique for measuring T
1
. In an inversion recovery measurement, a one-hundred eighty degree pulse is applied to a system of spins aligned along the static magnetic field in order to reverse the direction of the spins. The system of spins thus perturbed begins to decay toward their equilibrium direction according to T
1
. To measure the net magnetization, a ninety-degree pulse is applied to rotate the spins into the transverse plane and so induce a measurable signal. The signal will begin to decay as the spins dephase in the transverse plane, but the initial amplitude of the signal depends on the “recovery time” between the one-hundred eighty degree pulse and the ninety-degree pulse. By repeating this experiment for different recovery times and plotting the initial amplitude of the signal against recovery time, T
1
may be determined. While this technique has been successfully used in the laboratory for several years, inversion recovery is very time consuming, and those of ordinary skill in the art recognize that inversion recovery may be unsuitable for well logging applications.
Accordingly, there continues to be a general need for improved NMR measurements and, in particular for the oil and gas exploration industries, improved NMR methods that can be used to extract information about rock samples and be used in well-logging applications.
SUMMARY OF INVENTION
The invention provides a method for extracting information about a fluid that may be contained in rock or within a portion of earth formation surrounding a borehole (as used hereinafter, the term “rock” includes earth, earth formation, and a portion of earth formation). In one embodiment, the method involves applying a sequence of magnetic pulses to a fluid in a rock. The sequence includes a first part that is designed to prepare a system of nuclear spins in the fluid in a driven equilibrium followed by a second part that is designed to generate a series of magnetic resonance signals. The series of magnetic resonance signals is detected and analyzed to extract information about the fluid in the rock.
Further details and features of the invention will become more readily apparent from the detailed description that follows.
REFERENCES:
patent: 5023551 (1991-06-01), Kleinberg et al.
patent: 5381092 (1995-01-01), Freedman
patent: 5486762 (1996-01-01), Freedman et al.
patent: 5936405 (1999-08-01), Prammer et al.
patent: 2 342 170 (2000-04-01), None
patent: WO01/42817 (2001-06-01), None
Hurlimann et al. “Restricted Diffusion in Sedimentary Rocks. Determination of Surface-Area-to-Volume Ratio and Surface Relaxivity.”Journal of Magnetic Resonance, Series A 111(1994) pp. 169-178.
Journal of the American Chemical Society, 91:27, (1969), pp. 7784-7785, E. D. Becker et al., “A New Method for Nuclear Magnetic Resonance Enhancement”.
Journal of Magnetic Resonance, 8, (1972), pp. 298-310, R. R. Shoup et al., “The Driven Equilibrium Fourier Transform NMR Technique: An Experimental Study”.
Journal of Magnetic Resonance, 17, (1975), pp. 295-300, R. J. Kurland et al., “The Half-Wave Triplet Pulse Sequence for Determination of Longitudinal Relaxation Rates of Single Line Spectra”.
Journal of Magnetic Resonance, 17, (1975), pp. 301-313, H. T. Edzes, “An Analysis of the Use of Pulse Multiplets in the Single Scan Determination of Spin-Lattice Relaxation Rates”.
Journal of Molecular Spectroscopy, 35, (1970), pp. 298-305, J. S. Waugh, “Sensitivity in Fourier Transform NMR Spectroscopy of Slowly Relaxing Systems”.
SDR Research Note RDE (2001), Y-Q Song et al., “T1-T2Correlation Spectra Obtained Using a Fast Two-Dimensional Laplace Inversion”.
Siam J. Numerical Analysis, vol. 8, No. 3, (1981), pp. 381-397, J. P. Butler et al., “Estimating Solutions of First Kind Integral Equations with Nonnegative Constraints and Optimal Smoothing”.
Freed Denise
Hurlimann Martin D.
Scheven Ulrich
Terneaud Olivier J.
Venkataramanan Lalitha
Batzer William B.
DeStefanis Jody Lynn
Lefkowitz Edward
Ryberg John J.
Schlumberger Technology Corporation
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