NOx purifying catalyst

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Metal – metal oxide or metal hydroxide

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C502S527120, C502S527130, C502S304000, C502S325000, C502S349000, C502S344000, C502S340000

Reexamination Certificate

active

07662743

ABSTRACT:
The present invention provides an NOx purifying catalyst that removes NOx with sufficient efficiency even under low temperature operation such as diesel engine automobiles. An NOx purifying catalyst for processing NOx in exhaust gas by rich/lean control of the air-fuel ratio of the exhaust gas, includes a first catalytic layer containing β-zeolite having iron and/or cerium elements, and a second catalytic layer including a noble metal and cerium oxide-based material; in which the second and the first catalytic layers are coated on a support in that order so that the first catalytic layer is the uppermost layer. The NOx purifying catalyst purifies NOx as showed in Reaction Formulations (1) to (4).in-line-formulae description="In-line Formulae" end="lead"?Lean condition 1: NO+½O2→NO2  (1)in-line-formulae description="In-line Formulae" end="tail"?in-line-formulae description="In-line Formulae" end="lead"?Rich condition: CO+H2O→CO2  (2)in-line-formulae description="In-line Formulae" end="tail"?in-line-formulae description="In-line Formulae" end="lead"?NOx+H2→NH3  (3)in-line-formulae description="In-line Formulae" end="tail"?in-line-formulae description="In-line Formulae" end="lead"?Lean condition 2: NOx+NH3+O2→N2+H2O  (4).in-line-formulae description="In-line Formulae" end="tail"?

REFERENCES:
patent: 4961917 (1990-10-01), Byrne
patent: 5242677 (1993-09-01), Cooper et al.
patent: 5354720 (1994-10-01), Leyrer et al.
patent: 5473887 (1995-12-01), Takeshima et al.
patent: 6677264 (2004-01-01), Klein et al.
patent: 6825145 (2004-11-01), Tanada et al.
patent: 6953769 (2005-10-01), Yamada et al.
patent: 7214331 (2007-05-01), Jiang et al.
patent: 2001/0006934 (2001-07-01), Kachi et al.
patent: 2002/0187893 (2002-12-01), Yamada et al.
patent: 2004/0076565 (2004-04-01), Gandhi et al.
patent: 1 685 891 (2006-08-01), None
patent: 05-220403 (1993-08-01), None
patent: 06-316416 (1994-11-01), None
patent: 2600492 (1997-01-01), None
patent: 11-104493 (1999-04-01), None
patent: 11-300211 (1999-11-01), None
patent: 2004-120873 (2004-04-01), None
patent: 2006-281127 (2006-10-01), None
patent: 2006-314989 (2006-11-01), None
patent: 2007-167817 (2007-07-01), None
patent: 2007-181752 (2007-07-01), None
patent: 2007-313486 (2007-12-01), None
patent: 2007-330856 (2007-12-01), None
patent: WO 98/26867 (1998-06-01), None
patent: WO 02/41991 (2002-05-01), None
patent: WO 02/41991 (2002-05-01), None
patent: WO 2005/044426 (2005-05-01), None
patent: WO 2005/075059 (2005-08-01), None
Database WPI, Section Ch, Week 199043, Derwent Publications Ltd., London, GB, AN1990-327378, XP002455909.
Database WPI, Section Ch, Week 200254, Derwent Publications Ltd., London, GB, AN2002-508401, XP002455910.
He, N. et al., “Fe-containing mesoporous molecular sieves materials: very active Friedel-Crafts alkylation catalysts”, Applied Catalysis A: General, Elsevier Science, Apr. 17, 1998, pp. 29-36, vol. 169, No. 1, Amsterdam, NL.
Zhang K. et al., “Alkylation of phenol with tert-butyl alcohol catalysed by zeolite Hβ”, Applied Catalysis A: General, Elsevier Science, Jan. 2, 1998, pp. 89-95, vol. 166, No. 1, Amsterdam, NL.
Buchanan J. S., “Gasoline selective ZSM-5 FCC additives: Model reactions of C6-C10olefins over steamed 55:1 and 450:1 ZSM-5”, Applied Catalysis A: General, Elsevier Science, Jun. 29, 1998, vol. 171, No. 1, Amsterdam, NL.
Chen H-Y et al. “Reduction of NOxover various Fe/zeolite catalysts”, Applied Catalysis A: General, Elsevier Science, Mar. 13, 2000, pp. 159-168, vol. 194-195, Amsterdam, NL.
Gilot P. et al.; “A review of NOxreduction on zeolitic catalysts under diesel exhaust conditions”, Fuel, IPC Science and Technology Press, May 6, 1997, vol. 76, No. 6, Guildford, GB.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

NOx purifying catalyst does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with NOx purifying catalyst, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and NOx purifying catalyst will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4234595

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.