Novel uranium compounds, their preparation process and their use

Details Novel uranium compounds, their preparation process and their use Novel uranium compounds, their preparation process and their use

1985-03-22

1987-02-10

Terapane, John F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Radioactive metal containing

502152, 534 10, C07F 500, B01J 3100

Patent

active

046423370

ABSTRACT:
Novel uranium compounds, their preparation process and their use as catalysts for the hydrogenation of unsaturated organic compounds.
The uranium compounds are in accordance with formula: ##STR1## in which R.sup.1 represents an alkyl group, R.sup.2 an alkyl group, R.sup.3 an alkyl or aryl group, x is equal to 0 or is an integer between 1 and 5, m is equal to 1, 2 or 3, n is equal to 0, 1 or 2, p is equal to 1 or 2, provided m+n is equal to 3.
They can be used as catalysts for the hydrogenation of organic compounds, such as olefins, preferably dissolved in an organic solvent, such as tetrahydrofuran.

REFERENCES:
patent: 3920745 (1975-11-01), Floriani et al.
P. J. Fagan et al., "Synthesis and Properties of Bis(pentamethylcyclopentadienyl) Actinide Hydrocarbyls and Hydrides, A New Class of Highly Reactive f-Element Organometallic Compounds", JACS, 1981, 103, pp. 6650-6667.
Journal of the American Chemical Society, vol. 95, No. 1, 10 janvier 1973, pp. 91-93; A. E. Gebala et al; "Alpha-Bonded Organometallic Compounds of Uranium (IV)", *p. 91, abstract; p. 93, alinea 3*.

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