Novel trifluoromethyl benzal chlorides and process for the prepa

Organic compounds -- part of the class 532-570 series – Organic compounds – Halogen containing

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568437, C07B 900, C07C 1714, C07C 4500

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active

043673481

ABSTRACT:
Novel meta- and para-trifluoromethyl benzal chlorides and ring-halogenated derivatives are useful chemical intermediates for the preparation of meta- and para-trifluoromethyl benzaldehydes and various other useful end products. The novel compounds can be prepared from readily-available xylene starting materials in a process comprising (a) chlorinating meta- or para-xylene, or a ring -halogenated meta- or para-xylene, to form a trichloromethyl benzal chloride product and (B) reacting the trichloromethyl benzal chloride product with about 3 moles or less of anhydrous hydrogen fluoride in the presence of a halogen exchange catalyst.

REFERENCES:
patent: 2180772 (1939-11-01), Scherer
patent: 3465051 (1969-09-01), Pecherer
patent: 3489784 (1970-01-01), Feleg
patent: 3499934 (1970-03-01), Pyne
patent: 3681454 (1972-08-01), Rondestvedt
patent: 3813446 (1974-05-01), Jacobs
patent: 4079089 (1978-03-01), Klauke
patent: 4079090 (1978-03-01), Buttner
patent: 4093669 (1978-06-01), Klauke et al.
patent: 4229379 (1980-10-01), Bruhne et al.
Kobayashi et al., Accounts of Chem. Res. 11 (1978) pp. 197-204.
Hasek et al., J.A.C.S. 82 (1960) p. 543.
Mathey et al., Tetrahedron 31 (1975) pp. 391-401.
Belcher et al., Analytica Chimica Acta 10 (1954) pp. 34-47.
Fernandez-Bolanos et al., J. Chem. Soc. 1960, pp. 4003-4010.

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