Novel trialkyl aluminum cocatalyst

Compositions – Preservative agents – Anti-oxidants or chemical change inhibitants

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526139, 526141, 526142, C08F 464, C08F 468

Patent

active

041453131

ABSTRACT:
A new improved catalyst system for alpha-olefin type polymerizations, includes at least one metal alkyl compound having the formula R.sub.n MR'.sub.3-n in combination with a Group IVB-VIII transition metal compound on a support and at least one Lewis base wherein R is selected from the group consisting of C.sub.3 to C.sub.20 secondary or tertiary alkyl, cycloalkyl, alkenyl or aralkyl groups; R' is selected from the group consisting of C.sub.1 to C.sub.20 primary alkyl, alkenyl or aralkyl groups, or a hydride, M is selected from the group consisting of aluminum, gallium, or indium; and n = 1-3. The improved catalyst system provides polymers having increased isotactic stereo-regularity as well as lower catalyst residue.

REFERENCES:
patent: 3888789 (1975-06-01), Dombro et al.
patent: 3953414 (1976-04-01), Galli et al.
patent: 3992322 (1976-11-01), Dombro et al.

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