Novel polymers of alkyl methacrylates

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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560205, 560222, 560224, 560221, 2604482B, 2604659, 526279, 526310, 5263292, C07C 954

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active

040565599

ABSTRACT:
Polymers of esters of methacrylic acid having an average chain length of about 6 to about 50 mers are prepared by an anionic polymerization reaction, carried out in the presence of a chain-regulating alcohol and a catalytic amount of an alkoxide anion, in which control of the molecular weight and molecular weight distribution of the polymer are achieved by regulating the ratio of the total quantity of alcohol employed to the total monomer charge. These polymers, their hydrolysis products, and their derivatives have a wide variety of applications, including use as components in films, coatings, fibers, impregnants, adhesives, printing inks, and binders, and use as modifiers, plasticizers, melt flow improvers, and leveling agents.

REFERENCES:
patent: 2956990 (1960-10-01), Fettes
patent: 3317483 (1967-05-01), Verdol
patent: 3627820 (1971-12-01), Chujo

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