Novel polyacetal copolymers of trioxane and trimethylolpropane f

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From aldehyde or derivative thereof as reactant

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528241, 528245, 528247, 528250, C08G 400

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active

050047981

ABSTRACT:
Cationic copolymerization of trioxane and trimethylolpropane (TMP) formal or its ester derivatives yields acetal copolymers having pendant functional groups. The TMP formal or ester derivatives of TMP formal may therefore include functional groups selected from hydroxyl or ester moieties which are protected and thus survive the copolymerization with trioxane. These groups may then be present as functional reactive sites for the subsequent synthesis of block copolymers and/or to chemically bind modifiers to the acetal copolymer backbone, for example.

REFERENCES:
patent: 4076727 (1978-02-01), Zey et al.
patent: 4758608 (1988-07-01), Collins et al.
patent: 4792579 (1988-12-01), Satoh et al.
patent: 4876368 (1989-10-01), Broussard
CA 69:107263q, "Poly(Oxymethylene)".
CA 69:67927a, "Formaldehyde Glyoxal Bis(Trimethylolpropane Acetal) Polymers".
CA 101:193339c, "Polyoxymethylene Molding Compositions".

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