Novel pigment grinding vehicles

Chemistry of carbon compounds – Miscellaneous organic carbon compounds

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204181, 260 292TN, 260 296T, 260 37EP, C09C 310, C25D 1306

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active

039364054

ABSTRACT:
It has been found that quaternary onium (e.g., ammonium, sulfonium, and phosphonium) salt group-containing epoxy resins are particularly useful as grinding media in preparing stable pigment disperions useful in water-dispersible coating systems, for example, electrodepositable compositions. The resins are prepared by reacting a material selected from the group consisting of amine salts, phosphine-acid mixtures, and sulfide-acid mixtures with a 1,2-epoxy group containing material wherein a ratio of at least about 0.4 eqivalents of quaternary onium groups are produced per equivalent of epoxy group initially present. Preferably, the system contains at least a small amount of polyoxyalkylene glycol.

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patent: 3715335 (1973-02-01), Bacskai
patent: 3793278 (1974-02-01), DeBona
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