Novel phosphonocarboxylic acid compounds

Details Novel phosphonocarboxylic acid compounds Novel phosphonocarboxylic acid compounds

1979-09-10

1981-04-07

Poer, James

Compositions: coating or plastic

Coating or plastic compositions

Proteinaceous material containing

106315, C04B 1114

Patent

active

042604222

ABSTRACT:
Novel phosphonocarboxylic acid compounds having the formula ##STR1## wherein the radicals R which may be identical or different and which represent alkyl radicals with 1-18 carbon atoms which may be optionally substituted by halogen, hydrogen, alkali metal ions or ammonium ions, are prepared by reacting methylene phosphonic acid alkyl esters with acrylic acid esters in the presence of strongly basic catalysts at temperatures of about 0.degree.-140.degree. C., and by possibly trans-esterifying the reaction products or by submitting the latter to acid or basic hydrolysis. The acid hydrolysis to yield the free 3,3-diphosphono-pimelic acid is best carried out with at least the about 6-fold molar quantity of a carboxylic acid such as HCOOH, CH.sub.3 COOH, etc., optionally in the presence of catalytic quantities of strong acids or bases, at elevated temperatures.
The compounds of formula (I), wherein the radicals R represent only alkyl radicals which may possibly be substituted by halogen, are valuable plasticizers for polyvinyl chloride, the compounds of formula (I), wherein R=H, alkali metal ions and/or ammonium ions, are valuable gypsum setting retardants and complex-forming agents for metal ions.

REFERENCES:
patent: 3941772 (1976-03-01), Ploger et al.
patent: 4034086 (1977-07-01), Ploger et al.

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