Novel optically active alcohol

Details Novel optically active alcohol Novel optically active alcohol

1987-03-09

1989-05-30

Chan, Nicky

Organic compounds -- part of the class 532-570 series

Organic compounds

Heterocyclic carbon compounds containing a hetero ring...

549273, C07D30912

Patent

active

048352926

ABSTRACT:
(2R,3S,4R)-(+)- and (2S,3R,4S)-(-)-2,4-dimethyl-3-tetrahydropyranyloxy-1-heptanols which are important intermediates for synthesis of invictolide, one component of a queen recognition peromone of red imported fire ant.

REFERENCES:
Mori et al., Tet., 42(23), 6459 (1986).
Organic Chemistry, Pine et al., McGraw-Hill Int'l Book Co., pp. 118-119.
Rocca et al., "The Queen Recognition . . . (E)-6-(1-Pentenyl)-2H-Pyran-2-One", Tetrahedron Letters, vol. 24, No. 18, pp. 1889-1892, (1983).
Mori & Nakazono, "Synthesis of Both the Enantiomers . . . Fire Ant", Tetrahedron Letters, vol. 42, No. 23, pp. 6459-6464, (1986).
Senda & Mori, "Synthesis of (-)-Invictolide, . . . Fire Ant", Agric. Biol. Chem., 51, (5), 1379-1384, (1987).
Ann. Entomol. Soc. Am., 73 (5), 609-612 (1980) R. K. Vander Meer et al.
Tetrahedron Letters, 24(18), 1882-1892(1983) J. R. Rocca et al.

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