Novel multifunctional compounds and electrolytic oxidative coupl

Details Novel multifunctional compounds and electrolytic oxidative coupl Novel multifunctional compounds and electrolytic oxidative coupl

1987-02-19

1989-10-03

Niebling, John F.

Chemistry: electrical and wave energy

Processes and products

204 79, 204 80, 204294, C25B 300, C25B 1112

Patent

active

048714305

ABSTRACT:
A process for electrochemically coupling anions of organic radicals to form multifunctional compounds having the general formula ##STR1## in which R.sub.1 and R.sub.2 are independently selected from --CN, CO.sub.2 Et, --R .sub.4 CH.sub.2 Et, --CO.sub.2 R.sub.4, and --COCH.sub.3 ; R.sub.3 is Br, H, or Et, and R.sub.4 is C.sub.1-12 alkyl; and the novel compounds per se.

REFERENCES:
patent: 3759797 (1973-09-01), Masunaga et al.
patent: 4405816 (1983-09-01), Skaletz
patent: 4411746 (1983-10-01), Degner et al.
patent: 4434032 (1984-02-01), Baldwin et al.
patent: 4457810 (1984-07-01), Skaletz
Baizer, Organic Electrochemistry, Marcel Dekker, Inc., N.Y., N.Y., pp. 718-728 (1973).
White, "Synthesis with Electrogenerated Halogens", Journal of Electrochemical Society: Electrochemical Science and Technology, vol. 124, No. 8, 1177-1184, Aug. 1977.

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