Novel method for preparing organotin compounds

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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C07F 722

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040585441

ABSTRACT:
Triorganotin derivatives of polymerizable ethylenically unsaturated carboxylic acids are prepared either in the presence or absence of solvent by reacting the acid or a suitable derivative thereof with a triorganotin hydroxide or a bis(triorganotin)oxide. Polymerization of the acid or the triorganotin derivative thereof is avoided by using a dehydrating agent to remove the water formed as a by-product of the reaction.

REFERENCES:
patent: 2838554 (1958-06-01), Gloskey
patent: 3016369 (1962-01-01), Montermoso et al.
patent: 3167532 (1965-01-01), Leebrick
patent: 3257194 (1966-06-01), Miller
patent: 3555148 (1971-01-01), Katsumura et al.
Anderson, J. Org. Chem., v. 22, pp. 147-148 (1957).
Montermoso et al., J. Polymer Science, v. 32, pp. 523-525 (1958).
Shostakovski et al., J. Polymer Science, v. 52, pp. 223-229 (1961).
Matwiijoff et al., J. Organometal. Chem. 3, pp. 393-399 (1965).
Chemical Abstracts, v. 52, 16201e (1958).
Luijten et al., Investigations in the Field of Organotin Chemistry, England, pp. 104, 105, 107, 109 (1955).

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