Novel epoxy compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Unsubstituted hydrocarbyl chain between the ring and the -c-...

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540490, 540491, 540500, 540501, 540502, 540503, 544 2, 544 5, 544 6, 544 65, 544 66, 544 67, 544 71, 544183, 544220, 544230, 548122, 548123, 548124, 548126, 548410, 546 16, 546 20, C07D29104, C07D41904

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048959421

ABSTRACT:
Novel epoxyalkoxy-containing [4.4] spirodilactams having ring nitrogen atoms in the 1- and the 6- ring positions and having a substituent on each ring nitrogen atom, at least one of which substituents contains an epoxyalkyl moiety. Such epoxy compounds are produced by reaction of a 1-halo-2,3-epoxyalkane and the corresponding hydroxy-containing spirodilactam followed by treatment with strong base.

REFERENCES:
Blaha et al., Tetrahedron Letters, pp. 3949-3952 (1978), Polycyclic Dialatoms with Inherently Chiral Amide Chromophors.
Bijtas et al., CA 98:52962h (1982), The Mass Spectra of Some Spirodilactams.
The Encyclopedia of Polymer Science and Technology, vol. 6, pp. 209-222 (1968).
Cava et al, J. Am. Chem. Soc., vol. 77, 6022 (1955).
Cava et al, J. Am. Chem. Soc., vol. 79, pp. 1706-1709 (1956).
Pariza et al, Synthetic Communications, vol. 13(3), pp. 243-254 (1983).

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