Novel cyclopropane carboxylates

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514120, 514121, 514521, 558168, 558389, 558407, A61K 3119, A61K 31275, C07C25550, C07C22920

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050828320

ABSTRACT:
Novel 2,2-dimethyl-cyclopropane carboxylic acid derivatives of the formula ##STR1## wherein X.sub.1 and X.sub.2 are individually halogen, R.sub.1 is selected from the group consisting of halogen, alkyl of 1 to 8 carbon atoms, optionally substituted aryl of 6 to 14 carbon atoms, perfluoroalkyl of 1 to 8 carbon atoms, --CN and ##STR2## R' is alkyl of 1 to 8 carbon atoms, Y is selected from the group consisting of ##STR3## Alk.sub.1 is optionally unsaturated alkyl of 1 to 8 carbon atoms no substituted or substituted with at least one functional group, Ar is aryl of 6 to 14 carbon atoms no substituted or substituted with at least one functional group, Alk.sub.2 and Alk.sub.3 and Alk.sub.2 ' and Alk.sub.3 ' are optionally unsaturated alkyl of 1 to 8 carbon atoms no substituted or substituted with at least one functional group or together with ##STR4## form the rings ##STR5## wherein A is optionally unsaturated alkyl of 1 to 6 carbon atoms optionally substituted with at least one functional group, R" is alkyl of 1 to 6 carbon atoms no substituted or substituted with at least one functional group or aryl of 6 to 14 carbon atoms no substituted or substituted with at least one functional group and R is selected from the group consisting of hydrogen, alkyl of 1 to 8 carbon atoms and residue of an alcohol used in pyrethrinoid esters having pestioidal activity.

REFERENCES:
Tanaka et al. Chem. Abstracts, vol. 110, No. 7; 56687m (1989).
Fujita et al. Chem. Abstracts, vol. 109, No. 21; 190585j (1988).
Hiyama et al. Chem. Abstracts, vol. 109, No. 11; 91974d (1988).
Hiyama et al. Chem. Abstracts, vol. 107, No. 17; 154551v (1987).

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