Novel cationic epoxy resin esters and process of producing same

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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528 96, 528113, 2041817, C08G 5920, C08G 5940

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active

045799326

ABSTRACT:
Cationic epoxy resin esters suitable as binders for stoving coating compositions, particularly for application by electrodeposition, and as mill base resins for grinding pigments and extenders; and a process for producing same is described. The resin esters are produced through reaction of a resinous compound carrying at least two 1,2-epoxy groups with carboxylic acids and, optionally, with primary and/or secondary alkyl- and/or alkanolamines. The carboxylic acid employed, totally or partially, is the reaction product of a dicarboxylic acid anhydride and a tertiary amine which has the structure - ##STR1## wherein R and R.sub.x are a hydrogen atom or an alkyl radical or an aryl radical which may be substituted, R.sub.7 is an alkyl radical, an amino-alkyl radical having the primary amino groups, if present, blocked (as a ketimine) or the moiety remaining after the reaction with an active hydrogen atom of an acrylic or methacrylic monomer monofunctional with regard to the double bond, and wherein n is 2 or 3, the quantity of basic component being chosen in order that the epoxy-free final product has an amine value of at least 35, and preferably of from 40 to 140 mg KOH/g.

REFERENCES:
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patent: 4327200 (1982-04-01), Leitner et al.
patent: 4349655 (1982-09-01), Leitner et al.
patent: 4431781 (1984-02-01), Paar
patent: 4486280 (1984-12-01), Hosoi et al.

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