Chemistry: fischer-tropsch processes; or purification or recover – Group ib metal containing catalyst utilized for the...
Patent
1984-09-21
1986-02-04
Mars, Howard T.
Chemistry: fischer-tropsch processes; or purification or recover
Group ib metal containing catalyst utilized for the...
518714, 518716, 518717, 518719, 518720, 518721, 48197R, C07C 104
Patent
active
045686980
ABSTRACT:
Catalysts comprising a medium to large port zeolite modified by the oxide or acid of an element selected from the group consisting of Group IIIA to VIIA elements and, a Fischer-Tropsch catalyst wherein the ratio of zeolite to Fischer-Tropsch component is from about 0.1 to 50:1 can be employed to produce fuel grade saturated gaseous hydrocarbons from synthesis gas. A process is employed which includes the step of contacting synthesis gas over the foregoing catalyst at a reaction temperature of from about 100.degree. C. to 500.degree. C. and at a pressure of from about one atmosphere (0.1 MPa) to about 200 atmospheres (20 MPa) and at a gas hourly space velocity of from about 10 to 100,000. A method is also provided for the preparation of the combination catalyst. The catalyst and process for its use results in a small liquid aromatic product also being formed which is suitable for forming gasoline. Olefins and oxygenates are essentially eliminated.
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Desmond Michael J.
Pepera Marc A.
Evans Larry M.
Mars Howard T.
Pace Salvatore P.
The Standard Oil Company
Untener David J.
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