Novel catalysts and processes for the photochemical decarboxylat

Chemistry: electrical and wave energy – Processes and products – Electrostatic field or electrical discharge

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C07C 324

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045156670

ABSTRACT:
Alpha-hydroxy carboxylic acids, such as lactic acid and mandelic acid, are photochemically converted to form high yields of the corresponding alcohol by irradiating a solution containing the alpha-hydroxy carboxylic acid in contact with the semiconductor catalyst material. The semiconductor catalyst material is preferably a metal titanium oxide. The photochemical reaction may be carried out over a wide range of temperatures and pressures and in an oxidative or inert atmosphere.

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