Novel 2,6-dinitrophenyl selenium compounds and their use as epox

Details Novel 2,6-dinitrophenyl selenium compounds and their use as epox Novel 2,6-dinitrophenyl selenium compounds and their use as epox

1979-03-16

1980-12-30

Daus, Donald G.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

252439, 260550, C07C16300, C07D30112, B01J 2702

Patent

active

042422850

ABSTRACT:
Novel unsubstituted and 4-substituted, 2,6-dinitrophenyl seleninic acids, selenium halides and diselenides are described. The above-described selenium compounds are particularly useful to catalyze the oxidation of olefins to the corresponding epoxide in the presence of hydrogen peroxide.

REFERENCES:
patent: 3806467 (1974-04-01), Watanabe et al.
patent: 3953480 (1976-04-01), Delavarenne et al.
patent: 3993673 (1976-11-01), McMullen
P. Grieco et al, J. Org. Chem., 42, No. 11, pp. 2034-2036 (1977), Organoselenium Chemistry, Epoxidation of Olefins with Benzeneselenic Acid and H.sub.2 O.sub.2.
T. Hori et al, J. Org. Chem., 43, No. 9, pp. 1689-1696 (1978), Synthetic Applications of Arylselenic and Arylseleninic Acids, Conversion of Olefins to Allylic Alcohols and Epoxides.
E. Jeney et al., Chem. Abst. 55:16277b (1959), Bacteriostatic Action of Organic Selenocyanates.
D. Garratt et al, Chem. Abst. 82:139568c (1975), Addition of Arylselenium Trichlorides vs. Areneselenyl Chlorides to cis-and trans-1-phenylpropene.
H. Reich et al., Synthesis, No. 4, pp. 299-301 (1978), Seleninic Acids as Catalysts for Oxidation of Olefins and Sulfides using H.sub.2 O.sub.2.
N. Sonoda et al., Bull. Chem. Soc. Japan, 38, pp. 958-961 (1965).
M. Mugdan et al., J. Chem. Soc., pp. 2988-3000 (1949).
T. Austad, Chem. Abstr. 87:21898k (1977).

Affiliated with

Also associated with

Rating

Novel 2,6-dinitrophenyl selenium compounds and their use as epox does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Novel 2,6-dinitrophenyl selenium compounds and their use as epox, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Novel 2,6-dinitrophenyl selenium compounds and their use as epox will most certainly appreciate the feedback.

Rate now

Comments { 0 }

Profile ID: LFUS-PAI-O-6935