Nonyellowing cathodic electrocoat

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2041811, 2041817, 427409, 427410, 428413, 428418, C25D 1306, B32B 702, B32B 2738, B32G 1508

Patent

active

047554185

ABSTRACT:
A method of preventing the yellowing of the outermost coating of a multicoat coating system is disclosed. The method comprises initially depositing onto a conductive substrate by cathodic electrodeposition a primer coating comprising at least one layer of an amine-epoxy resin adduct and a cross-linking agent, and then curing said primer to a hard, durable film. Then, depositing a second coating onto the primer layer comprising at least one layer of a pigmented film-forming basecoat. Then depositing a third outermost coating onto the second coating comprising at least one layer of a clear, film-forming topcoat, and then curing the basecoat and topcoat. The primer coating contains a cross-linking agent selected from the group consisting of aliphatic polyisocyanates containing at least six carbon atoms, the isocyanurates of aliphatic polyisocyanates containing at least six carbon atoms, aromatic polyisocyanates having a molecular weight greater than 174, and the isocyanurates of aromatic diisocyanates having a molecular weight greater than 174. The polyisocyanates or isocyanurates are blocked with a blocking agent.

REFERENCES:
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patent: 4246151 (1981-01-01), Dohy et al.
patent: 4345004 (1982-08-01), Miyata et al.
patent: 4375498 (1983-03-01), Le Minez et al.
patent: 4456507 (1984-06-01), Kivel et al.
patent: 4508767 (1985-04-01), Hokamura et al.

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