Radiation imagery chemistry: process – composition – or product th – Imaged product – Structurally defined
Reexamination Certificate
2000-04-25
2001-06-05
Schilling, Richard L. (Department: 1752)
Radiation imagery chemistry: process, composition, or product th
Imaged product
Structurally defined
C430S496000, C430S502000, C430S510000, C430S533000, C430S534000, C430S950000
Reexamination Certificate
active
06242142
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to photographic materials. In a preferred form it relates to a photographic display image.
BACKGROUND OF THE INVENTION
It is known in the art that photographic display materials are utilized for advertising, as well as decorative displays of photographic images. Since these display materials are used in advertising, the image quality of the display material is critical in expressing the quality message of the product or service being advertised. Further, a photographic display image needs to be high impact, as it attempts to draw consumer attention to the display material and the desired message being conveyed. Typical applications for display material include product and service advertising in public places such as airports, buses and sports stadiums, movie posters, and fine art photography. The desired attributes of a quality, high impact photographic display material are a slight blue density minimum, durability, sharpness, and flatness. Cost is also important as display materials tend to be expensive compared with alternative display material technology mainly lithographic images on paper. For display materials, traditional color paper is undesirable, as it suffers from a lack of durability for the handling, photoprocessing, and display of large format images.
In the formation of color paper it is known that the base paper has applied thereto a layer of polymer, typically polyethylene. This layer serves to provide waterproofing to the paper, as well as providing a smooth surface on which the photosensitive layers are formed. The formation of a suitably smooth surface is difficult requiring great care and expense to ensure proper laydown and cooling of the polyethylene layers. The formation of a suitably smooth surface would also improve image quality as the display material would have more apparent blackness as the reflective properties of the improved base are more specular than the prior materials. As the whites are whiter and the blacks are blacker, there is more range in between and, therefore, contrast is enhanced. It would be desirable if a more reliable and improved surface for a display material could be formed at less expense.
Prior art photographic reflective papers comprise a melt extruded polyethylene layer which also serves as a carrier layer for optical brightener and other whitener materials, as well as tint materials. It would be desirable if the optical brightener and blue tints, rather than being dispersed in a single melt extruded layer of polyethylene could be concentrated nearer the surface of a display material where they would be more effective optically.
Prior art photographic transmission display materials with incorporated diffusers have light sensitive silver halide emulsions coated directly onto a gelatin coated clear polyester sheet or a gelatin coated clear polyester sheet containing white pigments. Incorporated diffusers are necessary to diffuse the light source used to backlight transmission display materials. Without a light diffuser, the light source would reduce the quality of the image. Typically, white pigments are coated in the bottommost layer of the imaging layers or are added to the polyester sheet. Since light sensitive silver halide emulsions tend to be yellow because of the gelatin used as a binder for photographic emulsions, minimum density areas of a developed image will tend to appear yellow. A yellow minimum density reduces the commercial value of a transmission display material because the imaging viewing public associates image quality with a white density minimum. It would be desirable if a transmission display material with an incorporated diffuser could have a density minimum with a blue tint, as a blue tinted density minimum is perceptually preferred by the public.
Prior art photographic translucent display materials with incorporated diffusers which include transmission and reflective display materials typically contain some level of white pigment to either diffuse the backlighting source in the case of transmission display materials or provide the desired reflective properties in the case of a reflective display material. While the use of white pigments in display materials does provide the desired diffusion and reflection properties, the white pigments tend to change the hue angle of the color dyes in a developed photographic display image. Dye hue angle is a measure in CIELAB color space of that aspect of color vision that can be related to regions of the color spectrum. For color photographic system there is a perceptual preferred dye hue angle for the yellow, magenta, and cyan dyes. It has been found that when photographic dyes are coated on support containing white pigments, the hue angle of the developed image changes compared to the hue angle of the dyes coated onto a transparent support. The hue angle change of photographic dyes caused by the presence of white pigments often reduces the quality level of the dyes compared to the dye set coated on a transparent base that is substantially free of white pigments. It would be desirable if a developed photographic dye set coated on a translucent support material had a dye hue angle that was not significantly different than the same dye set coated on a transparent support.
Prior art photographic display material use polyester as a base for the support. Typically the polyester support is from 150 to 250 &mgr;m thick to provide the required stiffness. A thinner base material would be lower in cost and allow for roll handling efficiency, as the rolls would weigh less and be smaller in diameter. It would be desirable to use a base material that had the required stiffness but was thinner to reduce cost and improve roll handling efficiency.
PROBLEM TO BE SOLVED BY THE INVENTION
There is a need for a photographic display material that provides less corruption of dye hue angle when coated on a translucent support while, at the same time, provides efficient diffusing of the illuminating light source such that the lighting elements of the light source are not apparent to the viewer.
SUMMARY OF THE INVENTION
It is an object of the invention to provide improved photographic display materials.
It is another object to provide photographic translucent display materials that have a maintained dye hue angle.
It is a further object to provide display materials that are low in cost, as well as providing sharp durable images.
These and other objects of the invention are accomplished by a photographic element comprising a base, a color forming layer comprising at least one silver halide emulsion layer and dye forming coupler, wherein said base comprises a translucent polymer sheet comprising a transparent polymer containing voids, wherein said translucent sheet is substantially free of white light reflecting pigments and wherein said translucent sheet has a light transmission of between 15% and 85%.
In another embodiment, the invention is accomplished by a display apparatus comprising a container provided with one side that is at least partially open or transparent, a light source adapted to provide light directed to the open or transparent side, means to suspend a photographic element comprising a base, a color layer formed by the reaction of at least one silver halide emulsion layer and dye forming coupler, wherein said base comprises a translucent polymer sheet comprising a transparent polymer containing voids, with the proviso that said translucent sheet is substantially free of white light reflecting pigments and said translucent sheet has a light transmission between 15% and 85% and is suspended in said one side that is at least partially open.
ADVANTAGEOUS EFFECT OF THE INVENTION
This invention provides brighter, snappy images by maintaining the dye hue of photographic dyes while, at the same time, allowing efficient diffusion of light used to illuminate display materials.
DETAILED DESCRIPTION OF THE INVENTION
The invention has numerous advantages over prior art photographic display materials and methods of imaging display materials.
Aylward Peter T.
Bourdelais Robert P.
Camp Alphonse D.
Eastman Kodak Company
Leipold Paul A.
Schilling Richard L.
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