Nonsludging zinc phosphating composition and process

Compositions: coating or plastic – Coating or plastic compositions – Corrosion inhibiting coating composition

Reexamination Certificate

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C106S014050, C106S014210, C148S253000, C148S256000, C148S275000, C205S080000, C205S124000, C205S197000, C205S217000, C205S219000, C205S318000, C205S320000, C205S323000

Reexamination Certificate

active

07422629

ABSTRACT:
Electrolysis using a suitable electrolyte provides a completely nonsludging zinc phosphate conversion coating process that produces a high quality conversion coating in a very short time. The suitable electrolyte contains at least water, dissolved nitric acid, and dissolved zinc cations and optionally also contains m chemically distinct species of cations other than zinc and n chemically distinct species of anions other than anions derivable by ionization of phosphoric and nitric acids, each of m and n independently being zero or a positive integer. Preferably, the liquid composition contains as additive at least one selection from nitrous acid, permanganic acid, peroxysulfuric acid, hydrogen peroxide, chloric acid, perchloric acid, nitrobenzenesulfonic acid, hydroxylamine, starch/phosphoric acid esters, fluorine compounds, and salts of the preceding; and/or the metal substrate is subjected to cathodic electrolysis after the workpiece has been brought into contact with a weakly basic aqueous colloidal solution that contains titanium oxide, titanium hydroxide, and zinc phosphate.

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