Nonlithographic method to produce masks by selective...

Coating processes – Nonuniform coating – Mask or stencil utilized

Reexamination Certificate

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Reexamination Certificate

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07485341

ABSTRACT:
A method for forming a self aligned pattern on an existing pattern on a substrate comprising applying a coating of the masking material to the substrate; and allowing at least a portion of the masking material to preferentially attach to portions of the existing pattern. The pattern is comprised of a first set of regions of the substrate having a first atomic composition and a second set of regions of the substrate having a second atomic composition different from the first composition. The first set of regions may include one or more metal elements and the second set of regions may include a dielectric. The masking material may comprise a polymer containing a reactive grafting site that selectively binds to the portions of the pattern. The masking material may include a polymer that binds to the portions of the pattern to provide a layer of functional groups suitable for polymerization initiation, a reactive molecule having functional groups suitable for polymerization propagation, or a reactive molecule, wherein reaction of the reactive molecule with the portion of the pattern generates a layer having reactive groups, which participate in step growth polymerization. Structures in accordance with the method. Compositions for practicing the method.

REFERENCES:
patent: 6025136 (2000-02-01), Drmanac
patent: 6423465 (2002-07-01), Hawker et al.
patent: 2002/0071943 (2002-06-01), Hawker et al.
patent: 2003/0068317 (2003-04-01), Lee et al.
patent: 2003/0108879 (2003-06-01), Klaerner et al.
patent: 1 035 218 (2000-09-01), None
patent: 1 081 163 (2001-03-01), None
Alger, Mark, Ed., Polymer Science Dictionary, Second Edition, Copyright 1989 Chapman & Hall, 1997 Mark Alger, definition of “graft copolymer” from p. 228.

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