Nonlinear optical crystals and their manufacture and use

Single-crystal – oriented-crystal – and epitaxy growth processes; – Processes of growth from liquid or supercritical state – Having growth from a solution comprising a solvent which is...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C117S070000, C117S071000, C117S075000

Reexamination Certificate

active

08062420

ABSTRACT:
Described are nonlinear optical (NLO) crystals, including aluminum-borate NLO crystals, that have low concentrations of contaminants that adversely affect the NLO crystal's optical properties, such as compounds that contain transition-metal elements and/or lanthanides, other than yttrium, lanthanum, and lutetium. Some NLO crystals with low concentrations of these contaminants are capable of second harmonic generation at very short wavelengths. Also described are embodiments of a method for making these NLO crystals. Some embodiments involve growing a single NLO crystal, such as an aluminum-borate NLO crystal, from a mixture containing a solvent that is substantially free of harmful contaminants. The described NLO crystals can be used, for example, in laser devices.

REFERENCES:
patent: 3057677 (1962-10-01), Ballman
patent: 4231838 (1980-11-01), Gier
patent: 4791927 (1988-12-01), Menger
patent: 4826283 (1989-05-01), Chuangtian et al.
patent: 5030851 (1991-07-01), Unternahrer et al.
patent: 5043308 (1991-08-01), Luetkens, Jr. et al.
patent: 5130996 (1992-07-01), Amano et al.
patent: 5202891 (1993-04-01), Sleight et al.
patent: 5684813 (1997-11-01), Keszler
patent: 5879803 (1999-03-01), Masaki et al.
patent: 6238593 (2001-05-01), Huguenin et al.
patent: 6419855 (2002-07-01), Keszler et al.
patent: 2004/0060501 (2004-04-01), Thomas et al.
patent: 2005/0247918 (2005-11-01), Keszler et al.
patent: 2006/0054864 (2006-03-01), Alekel et al.
patent: 2008/0014135 (2008-01-01), Alekel
patent: 1298217 (2001-06-01), None
patent: WO 00/15731 (2000-03-01), None
patent: WO 03/105238 (2003-12-01), None
patent: WO 2004/007352 (2004-01-01), None
Dekker et al., “Continuous wave and Q-switched diode-pumped neodymium, lutetium: yttrium aluminium borate lasers,”Optics Communications151:406-412, 1998.
Dekker et al., “2.27-WQ-switched self-doubling Yb:YAB laser with controllable pulse length,”J. Opt. Soc. Am. B22(2):378-384, Feb. 2005.
Jung et al., “Phase Transition of Neodymium Yttrium Aluminum Borate with Composition,”Materials Research Bulletin31(8):1021-1027, 1996.
Lu et al., “Excited Emission and Self-Frequency-Doubling Effect of NdxY1−xAl3(BO3)4Crystal,”Chinese Physics Letters3(9):413-416, 1986.
Leonyuk et al., “Entrance of impurities into yttrium aluminum borate crystals,” Izvestiia Akademii nauk SSR, Neorganicheskie materialy, vol. 12, Issue 7, pp. 1249-1251, 1976.
Beregi E. et al., “Growth and Morphology of Nd3+, Er3+and Cr3+doped YAl3(BO3)4Single Crystals,”Cryst. Res. Technol., 1999, 34(45-6): 641-645.
Brenier A., “Tunable Coherent Infrared Generation Near 2.5 μm from Self-Difference Frequency Mixing in YAl3(BO3)4:Nd3+,”Appl. Opt. 2004, 43:6007-6010.
Chen, C. et al., “Recent Advances in Nonlinear Optical and Electro-Optical Materials,”Ann. Rev. Mater. Sci., 1986, 16:203-243.
Durmanov S.T. et al. “Binary rare-earth scandium borate for diode-pumped lasers,”Optical Materials, 2001, 18:234-284.
Feigelson R.S., Byer R.L., Route R.K. and Joo G-t., “Search for New Nonlinear Optical Materials,”Center for Nonlinear Optical Materials Annual Report, C.3., 1995. 3 pages.
Gruber et al., “Spectroscopic properties of nonlinear NdSc3(BO3)4”,Journal of Applied Physics, May 15, 2000, 87(10): 7159-7163.
Jia G. et al., “Growth and Thermal and Spectral Properties of a New Nonlinear Optical Crystal TmAl3(BO3)4”,Crystal Growth and Design, 2005, 5(3):949-952.
Kellendonk F et al.,“On the Luminescence of Bismuth, Cerium, and Chromium and Yttrium Aluminium Borate,”J. Chem. Phys1982, 76(3):1194-1201.
Keszler, D. A., “Borates for optical frequency conversion,”J. Current Opinion in Solid State&Materials Science1996, vol. 1, pp. 204-211.
Kuz′min O.V. et al. “Cerium scandium borate—an active nonlinear medium for diode-pumped lasers,”Quantum Electronics, 1998, 28(1):50-54.
Leonyuk N. I. And Leonyuk L.I., “Growth and Characterization of RM3(BO3)4Crystals,”Prog. Crystal Growth and Charact. 1995, 31:179-278.
Li, J. et al., “The influence of Yb3+concentration on Yb:Al3(BO3)4,”Cryst. Res. Technol., 2003, 38(10):890-895.
Meyn, J. et al., “Spectroscopic Properties and Efficient Diode-Pumped Laser Operation of Neodymium-Doped Lanthanum Scandium Borate,”J. of Quantum Electronics, 1994, 30(4):913-917.
Mills A.D., Crystallographic Data for New Rare Earth Borate Compounds, RX3(BO3)4,Inorg. Chem, 1962, 1:960-961.
Ostroumov, V. et al., “Crystal growth, spectroscopic and laser characterization of Nd : CSB crystals,”J. of Luminescence, 1997, 72-74:826-828.
Peterson, G. A.,“Studies on New Solid-State Inorganic Borates and Oxoanion Fluorides.” Chapter 1, pp. 1-7, 1999 Ph.D. Thesis.
Peterson, G. A. et al., “Trigonal Huntite Borate CeSc3(BO3)4(CSB),” Chapter 2, pp. 14-32, 1999 Ph.D. Thesis.
Peterson G.A., Keszler D.A., and Reynolds T.A., “Stoichiometric, trigonal huntite borate CeSc3(BO3)4,”Intern. J. Inorg. Mater. 2000, 2:101-106.
Peterson, Dr. G. A., “Huntite Crystals for UV Nonlinear Optics and Self-Doubled Lasers,”Scientific Materials Corp., (Abstract Ballistic Missile Defense Organization Counsel, 2001.)
Wang, P. et al., “Growth and evaluation of ytterbium-doped yttrium aluminum borate as a potential self-doubling laser crystal,”J. Opt. Soc. Am. B., Jan. 1999, 16(1):63-69.
Ye, N. et al., “Nonlinear Optical Crystal YxLayScz(BO3)4(x+y+z=4),”Chem. Mater., 2005, 17:2687-2692.
Ye, N. et al., “Growth of nonlinear optical crystal Y0.57La0.72Sc2.71(BO3)4,”J. of Crystal Growth, 2006, 292:464-467.
Koporulina, E.V. et al., “Flux growth of (Y,RE)A13(BO3)4solid solutions (RE=Nd, Gd. Ho, Yb, Lu),”Journal of Crystal Growth, 211(1-4), pp. 491-496, Apr. 1, 2000.
Nikolov, V. et al., “A New Solvent for the Growth of Y1-XNDXAL3(BO3)4Single Crystals from High-Temperature Solutions,”Journal of Crystal Growth, 144(3/04), pp. 187-192, Dec. 2, 1994.
Supplementary European Search Report, Jan. 19, 2009.
Matthews, “The power in crystals,”LaserFocusWorld, Mar. 2003.

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Nonlinear optical crystals and their manufacture and use does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Nonlinear optical crystals and their manufacture and use, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Nonlinear optical crystals and their manufacture and use will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4305394

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.