Single-crystal – oriented-crystal – and epitaxy growth processes; – Processes of growth from liquid or supercritical state – Having growth from a solution comprising a solvent which is...
Reexamination Certificate
2007-06-19
2011-11-22
Kunemund, Bob M (Department: 1714)
Single-crystal, oriented-crystal, and epitaxy growth processes;
Processes of growth from liquid or supercritical state
Having growth from a solution comprising a solvent which is...
C117S070000, C117S071000, C117S075000
Reexamination Certificate
active
08062420
ABSTRACT:
Described are nonlinear optical (NLO) crystals, including aluminum-borate NLO crystals, that have low concentrations of contaminants that adversely affect the NLO crystal's optical properties, such as compounds that contain transition-metal elements and/or lanthanides, other than yttrium, lanthanum, and lutetium. Some NLO crystals with low concentrations of these contaminants are capable of second harmonic generation at very short wavelengths. Also described are embodiments of a method for making these NLO crystals. Some embodiments involve growing a single NLO crystal, such as an aluminum-borate NLO crystal, from a mixture containing a solvent that is substantially free of harmful contaminants. The described NLO crystals can be used, for example, in laser devices.
REFERENCES:
patent: 3057677 (1962-10-01), Ballman
patent: 4231838 (1980-11-01), Gier
patent: 4791927 (1988-12-01), Menger
patent: 4826283 (1989-05-01), Chuangtian et al.
patent: 5030851 (1991-07-01), Unternahrer et al.
patent: 5043308 (1991-08-01), Luetkens, Jr. et al.
patent: 5130996 (1992-07-01), Amano et al.
patent: 5202891 (1993-04-01), Sleight et al.
patent: 5684813 (1997-11-01), Keszler
patent: 5879803 (1999-03-01), Masaki et al.
patent: 6238593 (2001-05-01), Huguenin et al.
patent: 6419855 (2002-07-01), Keszler et al.
patent: 2004/0060501 (2004-04-01), Thomas et al.
patent: 2005/0247918 (2005-11-01), Keszler et al.
patent: 2006/0054864 (2006-03-01), Alekel et al.
patent: 2008/0014135 (2008-01-01), Alekel
patent: 1298217 (2001-06-01), None
patent: WO 00/15731 (2000-03-01), None
patent: WO 03/105238 (2003-12-01), None
patent: WO 2004/007352 (2004-01-01), None
Dekker et al., “Continuous wave and Q-switched diode-pumped neodymium, lutetium: yttrium aluminium borate lasers,”Optics Communications151:406-412, 1998.
Dekker et al., “2.27-WQ-switched self-doubling Yb:YAB laser with controllable pulse length,”J. Opt. Soc. Am. B22(2):378-384, Feb. 2005.
Jung et al., “Phase Transition of Neodymium Yttrium Aluminum Borate with Composition,”Materials Research Bulletin31(8):1021-1027, 1996.
Lu et al., “Excited Emission and Self-Frequency-Doubling Effect of NdxY1−xAl3(BO3)4Crystal,”Chinese Physics Letters3(9):413-416, 1986.
Leonyuk et al., “Entrance of impurities into yttrium aluminum borate crystals,” Izvestiia Akademii nauk SSR, Neorganicheskie materialy, vol. 12, Issue 7, pp. 1249-1251, 1976.
Beregi E. et al., “Growth and Morphology of Nd3+, Er3+and Cr3+doped YAl3(BO3)4Single Crystals,”Cryst. Res. Technol., 1999, 34(45-6): 641-645.
Brenier A., “Tunable Coherent Infrared Generation Near 2.5 μm from Self-Difference Frequency Mixing in YAl3(BO3)4:Nd3+,”Appl. Opt. 2004, 43:6007-6010.
Chen, C. et al., “Recent Advances in Nonlinear Optical and Electro-Optical Materials,”Ann. Rev. Mater. Sci., 1986, 16:203-243.
Durmanov S.T. et al. “Binary rare-earth scandium borate for diode-pumped lasers,”Optical Materials, 2001, 18:234-284.
Feigelson R.S., Byer R.L., Route R.K. and Joo G-t., “Search for New Nonlinear Optical Materials,”Center for Nonlinear Optical Materials Annual Report, C.3., 1995. 3 pages.
Gruber et al., “Spectroscopic properties of nonlinear NdSc3(BO3)4”,Journal of Applied Physics, May 15, 2000, 87(10): 7159-7163.
Jia G. et al., “Growth and Thermal and Spectral Properties of a New Nonlinear Optical Crystal TmAl3(BO3)4”,Crystal Growth and Design, 2005, 5(3):949-952.
Kellendonk F et al.,“On the Luminescence of Bismuth, Cerium, and Chromium and Yttrium Aluminium Borate,”J. Chem. Phys1982, 76(3):1194-1201.
Keszler, D. A., “Borates for optical frequency conversion,”J. Current Opinion in Solid State&Materials Science1996, vol. 1, pp. 204-211.
Kuz′min O.V. et al. “Cerium scandium borate—an active nonlinear medium for diode-pumped lasers,”Quantum Electronics, 1998, 28(1):50-54.
Leonyuk N. I. And Leonyuk L.I., “Growth and Characterization of RM3(BO3)4Crystals,”Prog. Crystal Growth and Charact. 1995, 31:179-278.
Li, J. et al., “The influence of Yb3+concentration on Yb:Al3(BO3)4,”Cryst. Res. Technol., 2003, 38(10):890-895.
Meyn, J. et al., “Spectroscopic Properties and Efficient Diode-Pumped Laser Operation of Neodymium-Doped Lanthanum Scandium Borate,”J. of Quantum Electronics, 1994, 30(4):913-917.
Mills A.D., Crystallographic Data for New Rare Earth Borate Compounds, RX3(BO3)4,Inorg. Chem, 1962, 1:960-961.
Ostroumov, V. et al., “Crystal growth, spectroscopic and laser characterization of Nd : CSB crystals,”J. of Luminescence, 1997, 72-74:826-828.
Peterson, G. A.,“Studies on New Solid-State Inorganic Borates and Oxoanion Fluorides.” Chapter 1, pp. 1-7, 1999 Ph.D. Thesis.
Peterson, G. A. et al., “Trigonal Huntite Borate CeSc3(BO3)4(CSB),” Chapter 2, pp. 14-32, 1999 Ph.D. Thesis.
Peterson G.A., Keszler D.A., and Reynolds T.A., “Stoichiometric, trigonal huntite borate CeSc3(BO3)4,”Intern. J. Inorg. Mater. 2000, 2:101-106.
Peterson, Dr. G. A., “Huntite Crystals for UV Nonlinear Optics and Self-Doubled Lasers,”Scientific Materials Corp., (Abstract Ballistic Missile Defense Organization Counsel, 2001.)
Wang, P. et al., “Growth and evaluation of ytterbium-doped yttrium aluminum borate as a potential self-doubling laser crystal,”J. Opt. Soc. Am. B., Jan. 1999, 16(1):63-69.
Ye, N. et al., “Nonlinear Optical Crystal YxLayScz(BO3)4(x+y+z=4),”Chem. Mater., 2005, 17:2687-2692.
Ye, N. et al., “Growth of nonlinear optical crystal Y0.57La0.72Sc2.71(BO3)4,”J. of Crystal Growth, 2006, 292:464-467.
Koporulina, E.V. et al., “Flux growth of (Y,RE)A13(BO3)4solid solutions (RE=Nd, Gd. Ho, Yb, Lu),”Journal of Crystal Growth, 211(1-4), pp. 491-496, Apr. 1, 2000.
Nikolov, V. et al., “A New Solvent for the Growth of Y1-XNDXAL3(BO3)4Single Crystals from High-Temperature Solutions,”Journal of Crystal Growth, 144(3/04), pp. 187-192, Dec. 2, 1994.
Supplementary European Search Report, Jan. 19, 2009.
Matthews, “The power in crystals,”LaserFocusWorld, Mar. 2003.
Keszler Douglas A.
Ye Ning
Klarquist & Sparkman, LLP
Kunemund Bob M
State of Oregon acting by and through the State Board of higher
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