Nonlinear optical crystal optimized for Ytterbium laser host...

Compositions – Light transmission modifying compositions – Inorganic crystalline solid

Reexamination Certificate

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C252S647000, C372S021000, C372S022000, C117S013000, C117S081000, C117S944000

Reexamination Certificate

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07378042

ABSTRACT:
A material for harmonic generation has been made by substitutional changes to the crystal LaCa4(BO3)3also known as LaCOB in the form Re1xRe2yRe3zCa4(B03)3O where Re1 and Re2, (rare earth ion 1 and rare earth ion 2) are selected from the group consisting of Sc, Yttrium, La, Ce, Pr, Nd, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb, and Lu; Re3 is Lanthanum; and x+y+z=1.

REFERENCES:
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patent: 5123022 (1992-06-01), Ebbers et al.
patent: 6083319 (2000-07-01), Aka et al.
patent: 6146553 (2000-11-01), Wu et al.
patent: 6185236 (2001-02-01), Eichenholz et al.
patent: 6301275 (2001-10-01), Eichenholz et al.
patent: 6859467 (2005-02-01), Adams et al.
patent: WO 96/26464 (1996-08-01), None
Iwai, M. et al., “Crystal Growth and Optical Characterization of Rare-Earth (Re) Calcium Oxyborate ReCa4O(BO3)3(Re=Y or Gd) as New Nonlinear Optical Material”, Department of Electrical Engineering, Faculty of Engineering, Osaka University, Dec. 4, 1996, pp. 276-279.
Adams, J.J., et al., “LaCa4O(BO3)3(LaCOB)—A new nonlinear crystal from the GdCOB family”, UCRL-JC-138484 Abs & Sum, University of California, Lawrence Livermore National Laboratory, Apr. 2000, 2 pages.
Aka, G. et al, Linear and non-linear-optical properties of a new gadolinium calcium oxoborate crystal, Ca4GdO(BO3)3, J. Opt. Soc. Am. B/vol. 14, No. 9/Sep. 1997, pp. 2238-2247.
Norrestam, R., et al., Structural Investigations of New Calcium-Rare Earth (R) Oxyborates with the Composition Ca4RO(BO3)3, Chem. Mater. 1992, 4, pp. 737-743.

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