Nonlinear optical composites of metal cluster laden polymers

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428328, 428330, 4284259, 428913, 524439, 524440, 524441, 523457, 523458, 523459, 252582, 252600, B32B 516

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active

052347583

ABSTRACT:
Nonlinear optical composites with large third-order optical response compd of metal clusters uniformly dispersed in polymers are prepared by vapor deposition of a metal onto a cold support while simultaneously cocondensing a vapor of an organic material. Where the organic material is a monomer, it polymerizes either when it comes in contact of the metal and/or when the cold surface is warmed. The unpolymerized monomer is removed to yield a processable composite. When the organic material is a diluent, it deposits as a solid on the cold surface forming a dispersion of the solid metal clusters in the liquid diluent. A polymer solution is then mixed with the dispersion and the composite is formed after removal of the diluent and the solvent for the polymer.

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patent: 5026599 (1991-06-01), Koskenmaki
patent: 5187209 (1993-02-01), Hirai et al.
patent: 5190990 (1993-03-01), Eichmiller

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