Nonhygroscopic, anionic pentacoordinate silicate

Details Nonhygroscopic, anionic pentacoordinate silicate Nonhygroscopic, anionic pentacoordinate silicate

1982-07-12

1984-05-08

Shaver, Paul F.

Organic compounds -- part of the class 532-570 series

Organic compounds

Silicon containing

556464, 260349, 526 89, 526128, 526194, C07F 708, C07F 710, C07F 718

Patent

active

044476280

ABSTRACT:
Nonhygroscopic, anionic pentacoordinate silicate, for example, ##STR1## soluble in commonly used organic solvents, and useful as a source of fluoride, cyanide or azide anion and as a catalyst or cocatalyst in polymerization systems, for example, the polymerization of methyl methacrylate.

REFERENCES:
patent: 3355477 (1967-11-01), Frye
patent: 3360525 (1967-12-01), Frye
patent: 3455980 (1969-07-01), Frye
patent: 3508946 (1970-04-01), Plueddemann et al.
patent: 3555069 (1971-01-01), Frye
Clark, Chem. Rev. 80, 429, (1980).
Farnham et al., J. Am. Chem. Soc. 103, 4808, (1981).
Perrozzi et al., J. Am. Chem. Soc. 101, 1591, (1979).

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