Nonaqueous electrolyte solution and lithium secondary...

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method

Reexamination Certificate

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Details

C429S340000, C429S332000, C429S334000, C429S342000, C429S231100, C429S331000, C429S338000, C429S188000

Reexamination Certificate

active

07727677

ABSTRACT:
Disclosed is a lithium secondary battery which is excellent in battery characteristics such as long-term cycle characteristics, capacity and shelf life characteristics. Also disclosed is a nonaqueous electrolyte solution which can be used for such a lithium secondary battery. Specifically disclosed is a nonaqueous electrolyte solution for lithium secondary batteries obtained by dissolving an electrolyte salt in a nonaqueous solvent which is characterized by containing 0.01-10% by weight of a carboxylate compound represented by the general formula (I) below and 0.01-10% by weight or 0.01-10% by volume of a vinylene carbonate and/or 1,3-propane sultone. Also disclosed is a lithium secondary battery using such a nonaqueous electrolyte solution. (In the formula, R2represents a hydrogen atom or COOR3group, R1and R3respectively represent an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group or a phenyl group, and X represents an alkynylene group or an alkenylene group.)

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