Non-oxide sintered ceramic fibers

Compositions: ceramic – Ceramic compositions – Refractory

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264DIG19, C04B 3502

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active

051358956

ABSTRACT:
A high temperature, preferably polycrystalline, ceramic fiber having a selectable diameter of between 1 and 200 microns. The fiber is stable in an inert atmosphere at a temperature above about 1700.degree. C. and is often stable even in air at a temperature above 1500.degree. C. The fiber comprises a sintered ceramic powder having a maximum particle size less than the diameter of the fiber and an average particle size less than 0.2 times the diameter of the fiber. The ceramic powder is also stable in an inert atmosphere at a temperature above about 1700.degree. C. At least 90% of the ceramic is selected from borides, nitrides, carbides, and silicides. The fiber is characterized by a smooth surface and is preferably out of round.
The invention further comprises a textilable sinterable filament, comprising a flexible polymer matrix containing high temperature sinterable ceramic powder particles. The ceramic powder particles are selected from ceramic borides, nitrides, carbides, and silicides. The diameter of the filament is from 2 to 300 microns. The invention also comprises the method for making textilable filament by fiberizing a mixture of a polymer and a sinterable non-oxide fiber and the method wherein the high temperature ceramic fiber is prepared by sintering the textilable sinterable filament as previously described. The invention also includes composites containing such filaments.

REFERENCES:
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patent: 3760049 (1973-09-01), Borer et al.
patent: 3808015 (1974-04-01), Seufert
patent: 3846527 (1974-11-01), Winter et al.
patent: 3909278 (1975-09-01), Johnson
patent: 3992498 (1976-11-01), Molton et al.
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patent: 4071594 (1978-01-01), Pearson et al.
patent: 4117057 (1978-09-01), Yajima et al.
patent: 4123286 (1978-10-01), Coppola et al.
patent: 4158687 (1979-06-01), Yajima et al.
American Ceramic Society Bulletin, vol. 66, No. 8, Aug. 1987.

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