Non-noble metal catalysts for the oxygen reduction reaction

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Plural component system comprising a - group i to iv metal...

Reexamination Certificate

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C502S215000, C502S216000, C502S219000, C502S220000, C502S222000, C423S509000, C423S561100

Reexamination Certificate

active

07125820

ABSTRACT:
Non-noble metal transition metal catalysts can replace platinum in the oxidation reduction reaction (ORR) used in electrochemical fuel cells. A RuxSe catalyst is prepared with comparable catalytic activity to platinum. An environmentally friendly aqueous synthetic pathway to this catalyst is also presented. Using the same aqueous methodology, ORR catalysts can be prepared where Ru is replaced by Mo, Fe, Co, Cr, Ni and/or W. Similarly Se can be replaced by S.

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Bron, M. et al., “Influence of Selenium on the Catalytic Properties of Ruthenium-Based Cluster Catalysts for Oxygen Reduction,”J. of Electroanalytical Chemistry 500:510-517, 2001, month unknown.
Trapp, V. et al., “New Catalysts for Oxygen Reduction Based on Transition-Metal Sulfides,”J. Chem. Soc., Faraday trans., 92(21):4311-4319, 1996, month unknown.
Tributsch, H. et al., “Methanol-Resistant Cathodic Oxygen Reduction Catalysts for Methanol Fuel Cells,”J. App. Electrochem.31:739-748, 2001, month unknown.

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