Non-linear optically active polycarbonate

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From phenol – phenol ether – or inorganic phenolate

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385145, 428 1, 525461, 525462, 525463, 525464, 525465, 525467, 525468, 528196, 528198, 528199, 528201, C08G 6400

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active

056888961

ABSTRACT:
The invention pertains to a non-linear optically active (NLO) side chain polycarbonate and to NLO active waveguides containing said polycarbonate. Waveguides containing this NLO polycarbonate have a low loss of signal. Polycarbonates based on bischloroformates of hexafluorobisphenol A, hexafluorotetrabromobisphenol A and bisphenol S or deuterated bisphenol A or sulphonylbiphenol are especially preferred within the framework of the invention: they were found to give an exceptionally low loss of signal. The invention further pertains to cross-linkable and already cross-linked polycarbonates. Especially preferred polycarbonates according to the invention are those where the diol comprises a rigid donor group. These polycarbonates have a high Tg, which renders them thermally stable.

REFERENCES:
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patent: 5208299 (1993-05-01), Bales et al.
T. Hoekstra al., "Photoluminescence and Attenuation of Spray-Pyrolysis-Deposited Erbium-Doped Y.sub.2 O.sub.3 Planar Optical Waveguides", Optics Letters, vol. 17, No. 21 (1992), pp. 1506-1508.
Chemical Abstracts, vol. 113, 192148g (1990).
Derwent Patent Abstract 88-311005/44, abstracting JP 63/228,135 (Sep. 22, 1988).
Kirk-Othmer Encyclopedia of Chemical Technology, Third Edition, vol. 18, pp. 491-492.
Encyclopedia of Polymer Science and Engineering, John Wiley & Sons, vol. 11, pp. 680, 683-687.
Comp. Poly. Sci.: The Synthesis, Characterization, Reactions and Applications of Polymers, vol. 5, Chapter 20, pp. 345-356.
Angew. Makromol. Chem. (1990), 183: pp. 251-252.

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