Non-linear optical devices and materials therefor

Optical: systems and elements – Optical frequency converter – Harmonic generator

Reexamination Certificate

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Reexamination Certificate

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07081984

ABSTRACT:
Materials suitable for use in non-linear optical devices comprise morpholinium or thiomorpholinium salts of hydroxy-substituted aliphatic or aromatic carboxylic acids selected from tartaric acid and hydroxy-substituted benzoic and cinnamic acids, which salts have a non-centrosymmetric crystalline form. Preferred salts include morpholinium 3-hydroxybenzoate, morpholinium 4-hydroxybenzoate, morpholinium 3,5-dihydroxybenzoate, morpholinium 3-fluoro-4-hydroxybenzoate, dimorpholinium 2,3,5,6-tetrafluoro-4-hydroxybenzoate, morpholinium 4-(4-hydroxyphenyl)benzoate, morpholinium tartrate, morpholinium 4-hydroxycinnamate, thiomorpholinium 4-hydroxy-benzoate and thiomorpholinium 3,5-hydroxybenzoate.

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Hall et al, “Polymorphism and Nonlinear Optical Activity in Organic Crystals”, Journal of Crystal Growth 79 (1986) 745-751.

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