Non-centrosymmetric organometallic molecules, process of prepara

Details Non-centrosymmetric organometallic molecules, process of prepara Non-centrosymmetric organometallic molecules, process of prepara

1992-01-10

1993-04-06

Dees, Jose

Organic compounds -- part of the class 532-570 series

Organic compounds

Heavy metal containing

556136, 564227, 564251, 359321, C07F 108, C07F 1504, C07F 1506, C07G28100

Patent

active

052005410

ABSTRACT:
The products having general formula (I) ##STR1## in which R represents a C.sub.1 -C.sub.18 alkoxyl, C.sub.1 -C.sub.18 alkylthio, C.sub.1 -C.sub.18 monoalkylamino or C.sub.2 -C.sub.36 dialkylamino group, R.sub.1 represents a hydrogen atom or a C.sub.1 -C.sub.18 alkyl group, R.sub.2 and R.sub.3, identical or different, represent a hydrogen atom or a C.sub.1 -C.sub.18 alkoxyl group and M represents a cobalt, nickel or copper atom, process of preparation, intermediates and use of the intermediates in order to obtain a product having general formula (I).

REFERENCES:
patent: 4807968 (1989-02-01), Leslie
patent: 4885113 (1989-12-01), Gillberg-LaForce et al.
patent: 5035839 (1991-07-01), Dorsch et al.
patent: 5119228 (1992-06-01), Fang
Chemical Abstracts, vol. 96, No. 19, May 10, 1982, p. 678, Abstract No. 161862e, Columbus, Ohio, US; B. E. Zaitzev et al.: "Synthesis and study of ligands containg a hydrazone group". VIII. Structure of glyoxal imine hydrazones & Zh. Obshch. Khim. 1982. vol. 52, No. 1 pp. 49-58.
Chemical Abstracts, vol. 94, No. 6, Feb. 9, 1981, p. 445, Abstract No. 37300q, Columbus, Ohio, US: K. P. Balakrishnan et al.: "Mode of coordination and chemical reactivity of alpha-imine hydrazone ligands" & J. Coord. Chem. 1980, vol. 10, No. 3, pp. 181-186.
Chemical Abstracts, vol. 92, Jun. 16-30, 1980, p. 681, Abstract No. 208144g, Columbus, Ohio, U.S.; K. P. Balakrishnan et al.: "Coordination behavior of imino hydrazone ligands towards nikcel (III) and copper (II) ions." & Synth. React. Inorg. Met. -Org. Chem. 1980, vol. 10, No. 1, pp. 73-81.

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