Non-aqueous electrolytes for lithium electrochemical cells

Chemistry: electrical current producing apparatus – product – and – Current producing cell – elements – subcombinations and... – Include electrolyte chemically specified and method

Reexamination Certificate

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C429S188000, C429S203000, C429S338000, C429S339000, C429S341000, C429S342000, C429S337000, C429S231800, C429S231950, C429S231100, C429S324000

Reexamination Certificate

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06852446

ABSTRACT:
A non-aqueous electric current producing electrochemical cell is provided comprising an anode and a cathode, an ionically permeable separator interposed between the anode and the cathode, and a non-aqueous electrolyte, the electrolyte comprising an ionically conducting salt in a non-aqueous medium, the ionically conducting salt corresponding to the formula:in-line-formulae description="In-line Formulae" end="lead"?M+(Z*(J*)j(X*)x)−,in-line-formulae description="In-line Formulae" end="tail"?wherein:M is a lithium atom,Z* is an anion group containing two or more Lewis basic sites and comprising less than 50 atoms not including hydrogen atoms,J* independently each occurance is a Lewis acid coordinated to at least one Lewis basic site of Z*, and optionally two or more such J* groups may be joined together in a moiety having multiple Lewis acidic functionality,X* independently each occurrence is selected from the group consisting of H, C1-C4alkyl, alkoxide, halide and mixtures thereof,j is an integer from 2 to 12, andx is an integer from 0 to 4.

REFERENCES:
patent: 6022643 (2000-02-01), Lee et al.
patent: 6395671 (2002-05-01), LaPointe
patent: 2002-260734 (2002-09-01), None
Lee et al. “The Synthesis of a New Family of Boro-Based Anion Receptors and the Study of Their Effect in Ion Pair Dissociation and Conductivity of Lithium Salts in Nonaqueous Solutions” J.Electrochem. Soc., vol. 145, No. 8, Aug. 1998, pp. 2813-2818.*
Sun et al. “Comparative Studies of the Electrochemical and Thermal Stability of Two Types of Composite Lithium Battery Electrolytes Using Boron-Based Anion Receptors” Journal of the Electrochemical Society, 146 (10), 1999, pp. 3655-3659.*
LaPointe et al. “New Family of Weakly Coordinating Anions” J. Am. Chem. Soc. 2000, 122, pp. 9560-0561.

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